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1.
Sensors (Basel) ; 23(13)2023 Jul 06.
Artigo em Inglês | MEDLINE | ID: mdl-37448047

RESUMO

Detection of fatigue is extremely important in the development of different kinds of preventive systems (such as driver monitoring or operator monitoring for accident prevention). The presence of fatigue for this task should be determined with physiological and objective behavioral indicators. To develop an effective model of fatigue detection, it is important to record a dataset with people in a state of fatigue as well as in a normal state. We carried out data collection using an eye tracker, a video camera, a stage camera, and a heart rate monitor to record a different kind of signal to analyze them. In our proposed dataset, 10 participants took part in the experiment and recorded data 3 times a day for 8 days. They performed different types of activity (choice reaction time, reading, correction test Landolt rings, playing Tetris), imitating everyday tasks. Our dataset is useful for studying fatigue and finding indicators of its manifestation. We have analyzed datasets that have public access to find the best for this task. Each of them contains data of eye movements and other types of data. We evaluated each of them to determine their suitability for fatigue studies, but none of them fully fit the fatigue detection task. We evaluated the recorded dataset by calculating the correspondences between eye-tracking data and CRT (choice reaction time) that show the presence of fatigue.


Assuntos
Movimentos Oculares , Movimentos da Cabeça , Humanos , Frequência Cardíaca , Gravação de Videoteipe , Tempo de Reação , Movimentos da Cabeça/fisiologia
2.
Phys Chem Chem Phys ; 13(18): 8163-74, 2011 May 14.
Artigo em Inglês | MEDLINE | ID: mdl-21152623

RESUMO

We present the full quantum mechanical theory of the angular momentum distributions of photofragments produced in photolysis of oriented/aligned parent polyatomic molecules beyond the axial recoil limit. This paper generalizes the results of Underwood and Powis(28,29) to the case of non-axial recoil photodissociation of an arbitrary polyatomic molecule. The spherical tensor approach is used throughout this paper. We show that the recoil angular distribution of the angular momentum polarization of each of the photofragments can be presented in a universal spherical tensor form valid for photolysis in diatomic or polyatomic molecules, irrespective of the reaction mechanism. The angular distribution can be written as an expansion over the Wigner D-functions in terms of the set of the anisotropy-transforming coefficients c(K(i)q(i))(K) (k(d), K(0)) which contain all of the information about the photodissociation dynamics and can be either determined from experiment, or computed from quantum mechanical theory. An important new conservation rule is revealed through the analysis, namely that the component q(i) of the initial reagent polarization rank K(i) and the photofragment polarization rank K onto the photofragment recoil direction k is preserved in any photolysis reaction. Both laboratory and body frame expressions for the recoil angle dependence of the photofragment angular momentum polarization are presented. The parent molecule polarization is shown to lead to new terms in the obtained photofragment angular distributions compared with the isotropic case. In particular, the terms with |q(i)| > 2 can appear which are shown to manifest angular momentum helicity non-conservation in the reaction. The expressions for the coefficients c(K(i)q(i))(K) (k(d), K(0)) have been simplified using the quasiclassical approximation in the high-J limit which allows for introducing the dynamical functions and the rotation factors which describe the decreasing of the photofragment angular momentum orientation and alignment due to the rotation of the molecular axis during photodissociation. In this case, the resultant recoil angle dependence is also presented in a form where the anisotropy of the parent molecular ensemble is expressed in terms of the molecular axis distribution, rather than in terms of the molecular density matrix.

3.
J Chem Phys ; 130(13): 134312, 2009 Apr 07.
Artigo em Inglês | MEDLINE | ID: mdl-19355737

RESUMO

We present the full quantum mechanical expressions for the polarization differential cross sections of the photofragments produced in slow predissociation of a parent molecule via isolated rotational branches. Both radial and Coriolis nonadiabatic interactions between the molecular potential energy surfaces have been taken into account. The expressions describe the recoil angle distribution of the photofragments and the distributions of the photofragment angular momentum polarization (orientation and alignment) in terms of the anisotropy parameters of the ranks K=0,1,2. The explicit expressions for the anisotropy parameters are presented and analyzed which contain contributions from different possible photolysis mechanisms including incoherent, or coherent optical excitation of the parent molecule followed by the radial, or Coriolis nonadiabatic transitions to the dissociative states. The obtained expression for the zeroth-rank anisotropy parameter beta is valid for any molecule and for an arbitrary value of the molecular total angular momentum J. The expressions for the orientation (K=1) and alignment (K=2) anisotropy parameters are given in the high-J limit in terms of the generalized dynamical functions which were analyzed for the case of photolysis of linear/diatomic molecules. As shown, the Coriolis nonadiabatic interaction results in several new photolysis mechanisms which can play an important role in the predissociation dynamics.

4.
J Chem Phys ; 127(4): 044308, 2007 Jul 28.
Artigo em Inglês | MEDLINE | ID: mdl-17672691

RESUMO

We present the quantum mechanical expressions for the angular momentum distribution of the photofragments produced in slow predissociation. The paper is based on our recent theoretical treatment [J. Chem. Phys. 123, 034307 (2005)] of the recoil angle dependence of the photofragment multipole moments which explicitly treat the role of molecular axis rotation on the electronic angular momentum polarization of the fragments. The electronic wave function of the molecule was used in the adiabatic body frame representation. The rigorous expressions for the fragment state multipoles which have been explicitly derived from the scattering wave function formalism have been used for the case of slow predissociation where a molecule lives in the excited quasibound state much longer than a rotation period. Possible radial nonadiabatic interactions were taken into consideration. The optical excitation of a single rotational branch and the broadband incoherent excitation of all possible rotational branches have been analyzed in detail. The angular momentum polarization of the photofragments has been treated in the high-J limit. The polarization of the photofragment angular momenta predicted by the theory depends on photodissociation mechanism and can in many cases be significant.

5.
J Chem Phys ; 123(3): 34307, 2005 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-16080737

RESUMO

We present the quantum-mechanical expressions for the recoil angle dependence of the photofragment multipole moments which explicitly treat the role of molecular axis rotation on the electronic angular momentum polarization of the fragments. The paper generalizes the result of Siebbeles et al. [J. Chem. Phys. 100, 3610 (1994)] to the case of dissociation of rotating molecules. The electronic wave function of the molecule was used in the adiabatic body-frame representation. The obtained rigorous expressions for the fragment state multipoles have been explicitly derived from the scattering wave-function formalism and then simplified using the quasiclassical approximation in the high-J limit. Possible radial and Coriolis nonadiabatic interactions have been taken into consideration. It is shown that the rotation of the molecular axis is described by a number of rotation factors which depend on the rank of the incident-photon polarization matrix, on the dissociation mechanism, and on the classical angle of rotation of the molecular axis gamma.

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